miliventure.blogg.se - Chemistry zen 4

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#Chemistry zen 4 pro

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The obtained results and insights are comprehensively discussed, including the relationship between the local structure of the active In/Ga species and reaction selectivity, as well as the influence of different zeolite frameworks on the formation of active species.Main article: Period (periodic table) Periods 1, 2 and 3 H He Li Be B C N O F Ne Na (sodium) Mg Al Si P S Cl Ar Furthermore, comparative studies on the formation of Ga-oxo clusters for POM at room temperature and the controlled formation of Ga-hydrides for selective EDH were conducted. Their detailed structures and reaction mechanisms are discussed in combination with spectroscopic, kinetic, and theoretical studies. We also observed the formation of In-hydrides in CHA zeolites during the preparation through reductive solid-state ion-exchange (RSSIE) and revealed their catalysis for non-oxidative C 2H 6 dehydrogenation (EDH). Our research group reported the formation of In–oxo clusters using the O 2 treatment of In-CHA and their potential for the partial oxidation of CH 4 (POM) at room temperature. In this perspective, we summarized our investigations on In- and Ga-exchanged zeolites for light-alkane transformations. In contrast, studies on In-exchanged zeolites have been far less explored, and thus active In-species have rarely been investigated. The speciation of active Ga species in reduced and oxidized Ga-exchanged zeolites and their reaction mechanisms have been discussed in several studies based on experimental and theoretical investigations.

Ga-exchanged zeolites have attracted attention as promising heterogeneous catalysts for dehydrogenative light-alkane transformations. Metal-exchanged zeolites have great potential to form unique active metal species and develop their catalysis by promoting small molecules such as light alkanes.